Surface grafting of electrochemically crosslinked poly(3,4-ethylenedioxythiophene) (PEDOT) brushes via surface-initiated ring-opening metathesis polymerization |
| |
| Authors: | Mustafa S Yavuz Gregory A Sotzing |
| |
| Institution: | 1. Department of Metallurgical and Materials Engineering, Selcuk University, Konya 42075, Turkey;2. Advanced Technology Research and Application Center, Selcuk University, Konya 42075, Turkey;3. Department of Chemistry and the Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, CT 06269-3136, United States |
| |
| Abstract: | Herein we demonstrated the preparation of 3,4-ethylenedioxythiophene (EDOT) containing polynorbornylene brushes on Au surfaces via surface-initiated ring-opening metathesis polymerization (SI-ROMP). Using solid-state oxidative crosslinking technique, these polymer brushes were electrochemically converted to conjugated polymer networks. Grazing-angle FTIR spectra of polymer brushes clearly showed the characteristic vibrations of EDOT and norbornylene groups. Furthermore, densely covered Au substrates with polynorbornylene brushes were characterized by using scanning electron microscopy and atomic force microscopy. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
