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Synthesis of planar chiral ferrocene alcohols as potential dendrimer cores
Authors:N. S. Khrushchev  V. I. Sokolov
Affiliation:(1) A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation
Abstract:Planar chiral compounds, 1-hydroxymethyl-2-methylferrocene and new 3-(2-hydroxymethylferrocenyl)propanol, were synthesized to be used as dendrimer cores. The ethers of these compounds, namely, 1-(benzyloxymethyl)-2-methylferrocene and 2-(benzyloxymethyl)-1-(benzyloxypropyl)ferrocene, can be regarded as zero-generation Freche type dendrimers. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1116–1119, July, 2006.
Keywords:ferrocenes  planar chirality  Freche type dendrimers  palladacycles
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