| 胶质碳球为模板制备NiO空心球 |
| |
| 引用本文： | 武拥建,郑明涛,谢春林,靳 权,易观贵,刘应亮.胶质碳球为模板制备NiO空心球[J].无机化学学报,2011,27(12):2447-2452. |
| |
| 作者姓名： | 武拥建 郑明涛 谢春林 靳 权 易观贵 刘应亮 |
| |
| 作者单位： | 暨南大学化学系,纳米化学研究所,广州 510632 |
| |
| 基金项目： | 国家-广东联合基金，国家自然科学青年基金，中央高校基本科研业务费专项资金 |
| |
| 摘 要： | 以胶质碳球为模板、六亚甲基四胺为沉淀剂,在乙醇中溶剂热反应,再经500℃煅烧6 h制备了NiO空心球。通过X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FTIR)和低温氮吸附-脱附,对NiO的结构和形貌进行了表征。结果表明溶剂热反应时间是制备完整NiO空心球的关键因素,溶剂热反应12 h,再经空气中煅烧,可制得形貌均一的NiO空心球。所得产物是由NiO纳米粒子组装而成的具有多孔结构的空心球。同时,本文对NiO空心球结构的形成过程和可能机理进行了分析和讨论。
|
| 关 键 词： | 氧化镍(NiO) 空心球 胶质碳球 溶剂热 |
Synthesis of NiO Hollow Spheres Using Colloidal Carbon Spheres as Template |
| |
| WU Yong-Jian,ZHENG Ming-Tao,XIE Chun-Lin,JIN Quan,YI Guan-Gui and LIU Ying-Liang.Synthesis of NiO Hollow Spheres Using Colloidal Carbon Spheres as Template[J].Chinese Journal of Inorganic Chemistry,2011,27(12):2447-2452. |
| |
| Authors: | WU Yong-Jian ZHENG Ming-Tao XIE Chun-Lin JIN Quan YI Guan-Gui and LIU Ying-Liang |
| |
| Institution: | Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632,Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632,Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632,Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632,Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 and Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 |
| |
| Abstract: | NiO hollow spheres were synthesized by a solvothermal reaction using colloidal carbon spheres (CCS) as sacricial template and hexamethylenetetramine (HMT) as precipitating agent in ethanol,and then calcined at 500 ℃ for 6 h.The characteristics of these NiO hollow spheres samples were characterized by XRD,SEM,TEM,FTIR and low temperature nitrogen adsorption-desorption isotherms.The results show that solvothermal reaction time is crucial to the integrity of the hollow spheres.The well defined NiO hollow spheres can be synthesized through 12 h solvothermal treatment and then calcination in air.The as-synthesized NiO hollow spheres have the porous wall consisted of nanosized particles.Moreover,the formation mechanism of NiO hollow spheres is also discussed. |
| |
| Keywords: | NiO hollow spheres colloidal carbon spheres solvothermal |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
