Synthesis of epoxyoxirano- and epoxydihydroxyisoindolones |
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| Authors: | F. I. Zubkov V. P. Zaytsev I. K. Airiyan V. D. Golubev E. S. Puzikova E. A. Sorokina E. V. Nikitina A. V. Varlamov |
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| Affiliation: | 1. Peoples?? Friendship University of Russia, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation
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| Abstract: | 1-Oxo-3a,6-epoxyisoindolones oxidized with potassium permanganate to give 4,5-dihydroxy-3a,6-epoxyisoindolones, while oxidation with peroxyformic acid or 3-chloroperoxybenzoic acid yielded 2,6a-epoxyoxirano[e]isoindolones. Oxidation proceeded with selective formation of exo-cis-adducts. |
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