Vibrational spectra of AuF5 complexes with nitrogen fluorides and oxofluorides |
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| Authors: | Sh Sh Nabiev V B Sokolov B B Chaivanov |
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| Institution: | 1. National Research Centre Kurchatov Institute, 1 pl. Kurchatova, 123182, Moscow, Russian Federation
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| Abstract: | Vibrational spectra and structural features of AuF5 complexes with nitrogen fluorides (NF3, N2F4) and oxofluorides (FNO, NF3O) are investigated. Vibrational frequency assignment in the solid phase and in solution of anhydrous HF was made. Distinctive features of vibrational spectra of X+AuF6 ? (X = NF4 +, N2F3 +, NO+, NOF2 +) related to structural transformations of cations and hexafluoroaurate anion due to the influence of the crystal field and cation-anion interactions are discussed. |
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