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Synthesis of 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes
Authors:L I Zakharkin  G G Zhigareva  E V Balagurova
Institution:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:The cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with organozinc compounds catalyzed by palladium complexes was used to synthesize the first representative ofB-phenyl-substituted carboranes, 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No: 6, pp. 1253–1254, June, 1998.
Keywords:π  -cyclopentadienyl-3  1  2-dicarbollylcobalt  catalysis  cross-coupling
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