Synthesis of 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10 by cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with C6H5ZnCl catalyzed by palladium complexes |
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Authors: | L I Zakharkin G G Zhigareva E V Balagurova |
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Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | The cross-coupling reaction of 9-I-3-(π-C5H5)-3,1,2-CoC2B9H10 with organozinc compounds catalyzed by palladium complexes was used to synthesize the first representative ofB-phenyl-substituted carboranes, 9-C6H5-3-(π-C5H5)-3,1,2-CoC2B9H10.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No: 6, pp. 1253–1254, June, 1998. |
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Keywords: | π -cyclopentadienyl-3 1 2-dicarbollylcobalt catalysis cross-coupling |
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