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An Unexpected Layered Structure in Inorganic Cyanide Clusters: [Cu4(μ3-OH)4][Re4(μ3-Te)4(CN)12] |
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| Authors: | Yuri V. Mironov Alexander V. Virovets Sofia B. Artemkina Vladimir E. Fedorov |
| Abstract: | Diffusion of aqueous solutions of K4[Re4Te4(CN)12] and CuCl2 in the opposite direction through silica gel gives rise to the new polymer-like compound 1 . This complex has a layered structure built from the interconnected cubane-like cluster cations [Cu4(μ3-OH)4]4+ and the cluster anions [Re4Te4(CN)12]4− (see picture). |
| Keywords: | Clusters Copper Cyanides Layered compounds Rhenium |