Ti2Nb6Cl14O4: A Unique 2D–1D Network Combination in Niobium Cluster Chemistry |
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Authors: | Ekaterina V. Anokhina Michael W. Essig Abdessadek Lachgar |
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Abstract: | Layers of niobium clusters that are linked to each other through zigzag chains of edge-sharing [TiCl4O2] ocatahedra are the central structural features of the title compound. Bridging of the chains by [(Nb6Cl8iO4i)Cl6a]6− clusters results in the formation of empty tunnels (a section of the structure is shown on the right). |
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Keywords: | Clusters Niobium Titanium |
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