|
|||||
|
|
Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4′-dimethyl-2,2′-bipyridine)iron(II) |
|
| Authors: | Jé rô me Lacour,Jonathan J. Jodry,Catherine Ginglinger,Sonya Torche-Haldimann |
| Abstract: | Two configurationally stable, chiral anions (TRISPHAT, 1 ) behave as efficient hosts that control the configuration of a configurationally labile iron(II ) complex as the guest with high diastereoselectivity (>96 % de) upon ion pairing. The diastereoselectivity increases with decreasing solvent polarity. |
| Keywords: | Asymmetric amplification Ion pairs Iron Phosphorus Supramolecular chemistry |