Novel Distorted Pentagonal-Pyramidal Coordination of Anionic Oxodiperoxo Molybdenum and Tungsten Complexes |
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| Authors: | Jean-Yves Piquemal,Sabine Halut,Jean-Marie Bré geault |
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| Abstract: | Model compounds for silica surfaces modified with metal complexes are provided by the mononuclear anionic diperoxo species 1 and the dinuclear complex anions 2 (M = Mo, W). They were obtained in fair to nearly quantitative yields by the reactions of Ph3SiOH and [Ph2Si(OH)]2O, respectively, with an aqueous solution of [MO(O2)2(H2O)2]. |
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| Keywords: | Molybdenum Peroxo complexes Si ligands Tungsten |
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