[{Y(OH)(Benzo-15-Krone-5)(CH3CN)}2]I4, ein Salz mit einem dimeren,hydroxidverbrückten out-of-cavity-Komplex |
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Authors: | Carsten Runschke Gerd Meyer |
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Abstract: | {Y(OH)(Benzo-15-Crown-5)(CH3CN)}2]I4, a Salt with a Dimeric Hydroxide-Bridged out-of-cavity Complex Coulorless single crystals of {Y(OH)(Benzo-15-Crown-5)(CH3CN)}2]I4 are obtained from the reaction of YI3 and benzo-15-crown-5 in acetonitrile. The crystal structure (monoclinic, P21/c, Z = 2, a = 1198.1(1), b = 1375.9(2), c = 1623.5(2) pm, β = 106.50(1)° R1 = 0.0843, wR2 = 0.2193 contains the hydroxide-bridged cationic out-of-cavity dimer. |
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Keywords: | Lanthanides Crystal structure Crown ether |
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