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Solid-Phase Synthesis of Oligosaccharides: Construction of a Dodecasaccharide |
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| Authors: | K C Nicolaou Nobuhide Watanabe Jim Li Joaquín Pastor Nicolas Winssinger |
| Abstract: | Complicated oligosaccharides such as dodecasaccharide 1 can be constructed by a new solid-phase strategy. The attachment to the polymeric support (gray sphere) is through a photolabile linker (structure I ), and thioglycosides serve as carbohydrate donors. Bn=benzyl, Bz=benzoyl. |
| Keywords: | Block-type construction Oligosaccharides Photolabile linker Solid-phase synthesis Thioglycoside |