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Quadruple Decker [3.3][3.3][3.3]Orthocyclophane Acetal—An Orthocyclophane Ladder |
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| Authors: | Shuntaro Mataka Kouichiro Shigaki Tsuyoshi Sawada Yoshihara Mitoma Masahiko Taniguchi Thies Thiemann Kazuya Ohga Naoyoshi Egashira |
| Abstract: | Through clever bridging of orthocyclophanes (in this case by acetalization), molecules such as 1 can be formed with four benzene rings in a stacked face-to-face arrangement. UV/Vis spectroscopic and electrochemical properties of 1 are governed by π–π through-space interactions within the molecule. |
| Keywords: | Cations Cyclic voltammetry Cyclophanes Stacking interactions |