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Synthesis,Electrochemistry, and Spectroscopy of Blue Platinum(II) Polyynes and Diynes |
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| Authors: | Muhammed Younus Anna Khler Stephane Cron Nazia Chawdhury Muna R A Al-Mandhary Muhammad S Khan Jack Lewis Nicholas J Long Richard H Friend Paul R Raithby |
| Abstract: | The smallest band gap observed so far (1.77 eV) for an organometallic polymer is exhibited by the blue, rigid-rod polymer 2 , which is prepared by the reaction of trans-PtCl2(PnBu3)2] with one equivalent of 1 . |
| Keywords: | Diyne complexes Electrochemistry Platinum Polymers UV/Vis spectroscopy |