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Metalloporphyrin Dendrimers with Folding Arms
Authors:Chi Ching Mak  Nick Bampos  Jeremy K M Sanders
Abstract:Rigid and flexible linkers are combined in the new dendrimer shown schematically in the picture, which contains nine metalloporphyrin units (Porph). The construction is such that the four “arms” of the dendrimer can fold in a cooperative and predetermined manner in response to added 1,4-diazabicyclo2.2.2]octane (DABCO).
Keywords:Cooperative effects  Coordination modes  Dendrimers  Porphyrinoids
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