The Hydrogen-Bonded Framework of the First Anti-Zeotype: [{(H2NEt2)2}2(CuCl4)][AlCl4] |
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| Authors: | James D Martin Brian R Leafblad |
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| Abstract: | A two-coordinate cationic link between CuCl4]3− tetrahedra by means of two inversion-related dialkylammonium cations yields the hydrogen-bonded A2X anti-cristobalite framework {(H2NEt2)2}2(CuCl4)]+. This novel cationic framework is constructed around space-filling and templating AlCl4]− anions resulting in large pores (16.6×6.7 Å). |
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| Keywords: | Clathrates Crystal engineering Hydrogen bonds Template synthesis Zeolite analogues |
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