Br3In · NH2Si(CH3)3 – ein stabiles Addukt des instabilen Trimethylsilylamins |
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| Authors: | S. Kü hner,H.-D. Hausen,J. Weidlein |
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| Abstract: | Br3In · NH2Si(CH3)3 – a Stable Adduct of the Unstable Trimethylsilylamine Heating a solution of indium tribromide in bis(trimethylsilyl)amine at about 55 °C for 30 to 35 hours the two adducts Br3In · NH2SiMe3 and Br3In · NH(SiMe3)2 are formed in a 3 : 1 molar ratio. Both compounds have been characterized by NMR, IR and Raman spectra; the X-ray structure determination of the title compound is reported. |
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| Keywords: | Trimethylsilylamine Indium tribromide adduct NMR vibrational spectra X-ray structure. |
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