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Darstellung und spektroskopische Charakterisierung von Perfluor(isopropyl)trifluoracetylperoxid (CF3)2C(F)OOC(O)CF3 |
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| Authors: | Rolf Minkwitz Stefan Reinemann |
| Abstract: | Preparation and Spectroscopic Characterization of Perfluoro(isopropyl)-trifluoroacetylperoxide (CF3)2C(F)OOC(O)CF3 The reaction of perfluoroacetone (CF3)2CO with OF2 in a ratio 2 : 1 yields Perfluoro(isopropyl)-trifluoroacetylperoxide (CF3)2C(F)OOC(O)CF3. The reaction only occurs under CsF-catalysis. (CF3)2C(F)OOC(O)CF3 is characterized by vibrational, nmr and mass spectra. Using an excess of OF2 does not give any stable product. |
| Keywords: | Perfluoro(isopropyl)trifluoroacetylperoxid Oxygendifluoride Peroxides Vibrational Spectra NMR Spectra |