N–O-Bindungsspaltung in O-silylierten Oximen bei der Reaktion mit einem Titanocen-Alkin-Komplex

N–O Bond Cleavage in O-silylated Oximes by Reaction with a Titanocene-Alkyne Complex Cp₂Ti(Me₃SiC₂SiMe₃) 1 reacts with alicyclic and aliphatic O-silylated ketoximes of type R¹R²C=NOSiMe₃ ( 2 : R¹R² = (CH₂)₅; 3 : R¹ = R² = Me) under N–O bond breaking to the titanocene complexes Cp₂Ti(OSiMe₃)(N=CR¹R²) 6 (R¹R² = (CH₂)₅) and 7 (R¹ = R² = Me). The structure of 6 was obtained by X-ray crystal structure analysis ( 6 : triclinic, space group P1, Z = 2, a = 9.486(1), b = 9.865(1), c = 12.305(2) Å, α = 107.19(1), β = 96.08(1), γ = 111.08(1)°).