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The π-Pyrrole Complexation of Alkali Metal Ions by Zirconium meso-Octaalkylporphyrinogens: Encapsulation of Li4H4 and Li2O in Sandwich Structures |
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| Authors: | Carlo Floriani Euro Solari Giovanna Solari Angiola Chiesi-Villa Corrado Rizzoli |
| Abstract: | Complexation of metal ion and counterion by the same compound is possible with zirconium meso-octaalkylporphyrinogens (structure of a dimeric complex with four encapsulated equivalents of LiH is depicted): they carry salts in the molecular ion-pair form in hydrocarbons, and function as acid–base bifunctional compounds. |
| Keywords: | Calixpyrroles Ion pairs Lithium Porphyrinogens |