|
|||||
|
|
A Monomeric d9-Rhodium(0) Complex |
|
| Authors: | Hartmut Schnberg Souad Boulmaz Michael Wrle Lorenz Liesum Arthur Schweiger Hansjrg Grützmacher |
| Abstract: | A pocket suitable for bonding transition metals is formed by the 5-phosphanyl group and the olefinic unit of the central seven-membered ring, which has a rigid boat conformation, of the ligand troppPh ( 1 ). This new ligand system allows the synthesis and isolation of stable d9 and d10 rhodium complexes 2 and 3 , respectively. |
| Keywords: | Electrochemistry ENDOR spectroscopy EPR spectroscopy P ligands Rhodium |