Cyanide attack at low-spin iron(II)–diimine complexes: the structure of a cyanide-containing derivative of a leaving ligand |
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Authors: | John Burgess John Fawcett |
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Affiliation: | (1) Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK |
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Abstract: | The isolation and structural characterisation of the product of addition of HCN to the Schiff base derived from phenyl 2-pyridyl ketone and 3,4-dimethylaniline (Me2bsb) provides evidence in favour of a mechanism involving nucleophilic attack at the coordinated ligand for reaction of the complex [Fe(Me2bsb)3]2+ with cyanide. |
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