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Synthesis and electrocatalytic properties of a dinuclear palladium(I) 1-[(2-bromo)benzene]-3-[(2-carboxymethyl)benzene]triazenide complex |
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| Authors: | Jing Chu Qi-ying Lv Xiao-hua Xie Wei Li Shuzhong Zhan |
| Affiliation: | 1. College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China 2. College of Chinese Language and Culture, Jinan University, Guangzhou, 510610, China 3. Department of Chemistry, Guizhou Minzu University, Guiyang, 550000, China |
| Abstract: | The reaction of 1-[(2-bromo)benzene]-3-[(2-carboxymethyl)benzene]triazene and [Pd(CH3CN)4]Cl2 gave a new dinuclear triazenido complex [Pd2L2] 1, which has been characterized by NMR spectra and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in CH2Cl2. |
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