Redox properties of rhodium diene-cyclopentadienyl complexes |
| |
| Authors: | N A Ustynyuk M G Peterleitner O V Gusev L I Denisovich |
| |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| |
| Abstract: | The electrochemical behavior of rhodium sandwich complexes containing η4-pentamethylcyclopentadiene or tetramethylfulvene fragments has been studied by cyclic voltammetry. The complexes undergo
one-electron oxidation to give unstable 17-electron radical cations which are converted into rhodocenium salts as a result
of elimination or uptake of hydrogen or C-C bond cleavage.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1802–1805, October, 1993. |
| |
| Keywords: | rhodium η -complexes electrochemistry one-electron oxidation |
| 本文献已被 SpringerLink 等数据库收录！ |
