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Direct influence of hydrogen-bonding on the reduction potential of a CuII center |
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| Authors: | Glaser Thorsten Liratzis Ioannis Kataeva Olga Fröhlich Roland Piacenza Manuel Grimme Stefan |
| Institution: | Lehrstuhl für Anorganische Chemie I, Fakult?t für Chemie, Universit?t Bielefeld, Universit?tsstr. 25, D-33615 Bielefeld, Germany. thorsten.glaser@uni-bielefeld.de |
| Abstract: | Two hydrogen-bonds from geometrically constrained OH groups to coordinated oxygen donors shift the reduction potential of a Cu(II) complex by +270 mV as compared to the structurally analogous reference complex missing the OH groups. |
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