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Effect of Surface States on the Electrochemical Behaviour of Single Crystal n-ZnSe Photoelectrode
Authors:M S El-Dessouki  F El-Kabbany  V A Attia
Abstract:Surface Photovoltage Spectroscopy (SPS) technique has been used to detect the surface states of ZnSe (110) surfaces. Aqueous electrolyte/ZnSe junction has been electrochemically investigated in dark and under illumination. The effect of surface states on the kinetics of charge transfer through the semiconductor-electrolyte (S/E) junction has been discussed. The low leakage and photocurrents measured by the application of D.C. bias were referred to the blocking nature of S/E interface, in which the localized and induced surface states play an important role.
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