Growth and electric properties of (100)-oriented Mn-doped (Bi0.5Na0.5)TiO3-BaTiO3 thin film by pulsed laser deposition |
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Authors: | Chengchao Jin Feifei Wang Chung Ming Leung Yanxue Tang Tao Wang Qirong Yao Wangzhou Shi |
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Institution: | 1. Key Laboratory of Optoelectronic Material and Device, Mathematics & Science College, Shanghai Normal University, Shanghai, 200234, China 2. Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong
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Abstract: | Mn-doped (Bi0.5Na0.5)TiO3-BaTiO3 (BNBMT) thin film with the composition near the morphotropic phase boundary was grown on (La0.6Sr0.4)CoO3-electroded SrTiO3 single-crystal substrate by using pulsed laser deposition method. Ascribed to the crystal structure and lattice similarity, (100)-oriented BNBMT film with pure single-phase perovskite structure was obtained through carefully controlling the growth conditions. Enhanced ferroelectric and dielectric properties were obtained with large remanent polarization P r of ~21 μC/cm2, coercive field E c of ~7.4 kV/mm and dielectric constant $\varepsilon_{33}^{T}/\varepsilon_{0}$ of ~750 at 1 kHz. The excellent global electrical properties of the BNBMT film are promising for environmentally friendly ferroelectric devices. |
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