A chiral cyclotrisazobiphenyl: synthesis and photochemical properties |
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Authors: | Reuter Raphael Wegner Hermann A |
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Affiliation: | Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland. |
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Abstract: | A chiral cyclotrisazobiphenyl macrocycle was synthesized conveniently in three steps from the literature known 3,3'-diaminobimesityl in 37-38% overall yield. Irradiation with 302 nm, 365 nm or visible light allows access to different photostationary states (PSSs). These PSSs can be conveniently read out by CD-spectroscopy as each of them exhibits a positive, a negative, or no signal, respectively, at 275 nm. |
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