An approach to the hexacyclic skeleton of trigonoliimines |
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Authors: | Feng Pengju Fan Yukai Xue Fazhen Liu Weigang Li Songlei Shi Yian |
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Affiliation: | Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. |
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Abstract: | A strategy to construct the hexacyclic skeleton of trigonoliimines A, B and their derivatives involving a carbanion-triggered intramolecular cyclization of a seven-membered ring and a subsequent six-membered ring formation in one pot is described. |
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