Ruthenium(II) <Emphasis Type="Italic">N</Emphasis>-heterocyclic Carbene Complexes in the Transfer Hydrogenation of Ketones |
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Authors: | Email author" target="_blank">Ismail??demirEmail author Sedat?Ya?ar Bekir??etinkaya |
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Institution: | 1.Faculty of Science and Arts, Chemistry Department,In?nü University,Malatya,Turkey;2.Department of Chemistry,Ege University,Bornova-?mir,Turkey |
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Abstract: | Six ruthenium-N-heterocyclic carbene complexes (2–7) have been prepared and the new compounds characterized by C, H, N analyses, 1H-n.m.r. and 13C-n.m.r. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes (2–7) in the presence of t-BuOK. |
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