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The Crystal Structures of Trimethylphosphane supported Nickel‐ and Cobalt‐Methyl Complexes: Octahedral mer‐cis‐[CoIIII(CH3)2(PMe3)3] and Square Planar trans‐[NiIICl(CH3)(PMe3)2]
Authors:Robert Beck  Hans‐Friedrich Klein
Abstract:Single crystals of octahedral mer‐cis‐[CoIIII(CH3)2(PMe3)3] ( 1 ) and square planar trans‐[NiIICl(CH3)(PMe3)2] ( 2 ), were obtained from solvent mixtures (methylcylohexane / pentane 1:1) and have been analyzed by X‐ray crystallography for the first time.
Keywords:Cobalt  Nickel  Phosphane  Crystal structure  C ligands
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