Di‐μ‐chlorido‐bis({2‐[1‐(2‐pyridylethylimino)ethyl]pyrrolato‐κ3N,N′,N′′}copper(II)) |
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Authors: | Rongqing Li Pusu Zhao Guodong Tang Xiaoling Tang |
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Abstract: | The title compound, Cu2(C13H14N3)2Cl2], is a neutral dimeric copper(II) complex. The two CuII atoms are asymmetrically bridged by two chloride ions. Each CuII atom is also bound to the three N atoms of a deprotonated tridentate Schiff base ligand, giving a distorted square‐pyramidal N3Cl2 coordination environment overall. The dinuclear complex lies across an inversion centre in the space group P. This work demonstrates the effect of ligand flexibility and steric constraints on the structures of copper(II) complexes. |
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