Electroreduction of CuO-V2O5 in sulfolane containing lithium perchlorate |
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| Authors: | N V Karichkovskaya V S Kolosnitsyn N N Krasnogorskaya L F Teregulova |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054 Bashkortostan, Russia;(2) Ufa State Technical University of Aviation, Ufa, Bashkortostan, Russia |
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| Abstract: | Variations in the composition of polymetallic oxide system V2O5-CuO are found to be accompanied by a gradual change in electrochemical properties. Average discharge voltage of copper vanadates
2CuO-V2O5 and 4CuO-V2O5 is higher than that of V2O5. The depth of electroreduction of 2CuO-V2O5,3CuO-V2O5, and 4CuO-V2O5 is, respectively, 3.32, 3.0, and 2.7 electrons per mole of vanadium, which is almost twice that of V2O5. |
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