Methylenecyclopropane as C1 synthetic units: [1+4] cycloaddition via a nickel catalyst |
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| Authors: | Inami Tasuku Kurahashi Takuya Matsubara Seijiro |
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| Affiliation: | Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan. |
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| Abstract: | Nickel-catalyzed reactions of methylenecyclopropanes and thioanhydrides afford sulfur-containing heterocyclic compounds via [1+4] cycloaddition. The reactions represent a new use for methylenecyclopropane as a possible one-carbon building block to replace carbon monoxide, isocyanides, and Fischer carbene complexes. |
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