Generation of Singlet Oxygen from Ozone Catalysed by Phosphinoferrocenes |
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Authors: | Email author" target="_blank">Walther G?JaryEmail author Thorsten?Ganglberger Peter?P?chlauer Heinz?Falk |
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Institution: | (1) DSM Fine Chemicals Austria, Research and Development, A-4021 Linz, Austria;(2) Institut für Organische Chemie, Johannes Kepler Universität, A-4040 Linz, Austria |
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Abstract: | Summary. A novel chemical source of singlet oxygen based on the conversion of ozone by 1,1 -bis(triphenylphosphino)ferrocene as catalyst was developed into a feasible method for a preperative scale. This is, to our best knowledge, the first application of substituted ferrocenes as oxidation catalysts. |
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Keywords: | , Ozone, Ozonation, Singlet oxygen, Catalysis, Ferrocenes, |
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