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Generation of Singlet Oxygen from Ozone Catalysed by Phosphinoferrocenes
Authors:Email author" target="_blank">Walther G?JaryEmail author  Thorsten?Ganglberger  Peter?P?chlauer  Heinz?Falk
Institution:(1) DSM Fine Chemicals Austria, Research and Development, A-4021 Linz, Austria;(2) Institut für Organische Chemie, Johannes Kepler Universität, A-4040 Linz, Austria
Abstract:Summary. A novel chemical source of singlet oxygen based on the conversion of ozone by 1,1prime-bis(triphenylphosphino)ferrocene as catalyst was developed into a feasible method for a preperative scale. This is, to our best knowledge, the first application of substituted ferrocenes as oxidation catalysts.
Keywords:, Ozone, Ozonation, Singlet oxygen, Catalysis, Ferrocenes,
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