THE P4 MOLECULE AND P4H+ ION |
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| Authors: | E Fluck C M E Pavlidou R Janoschek |
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| Institution: | 1. Institut für Anorganische Chemie;2. Institut für Theoretische Chemie, Universit?t Stuttgart , Pfaffenwaldring 55, D 7000, Stuttgart 80 |
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| Abstract: | Abstract Experimental findings as well as quantum chemical calculations indicate that the P4 molecule has a remarkably low nucleophilicity. The P4H+ ion is predicted to have a ‘proton at apex’ configuration whereas a proton in the centre seems to be metastable. The influence of d orbitals on the stability of P4 against 2 P2 and 1/2 P8, the photoelectron spectrum, and the valence electron density is discussed. |
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| Keywords: | benzoines Bi(NO3)3 5H2O solventless system |
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