E.P.R. STUDY OF THE ACTION OF NITROSO DERIVATIVES ON ORGANOPHOSPHORUS COMPOUNDS. II1—CASE OF 2-METHYL, 2-NITROSOPROPANE (M.N.P.) |
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| Authors: | P Tordo M Boyer V Cerri F Vila |
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| Institution: | Laboratoire de Chimie Organique Physique de l' , Université de Provence Rue Henri Poincaré , 13397, Marseille Cedex 4, France |
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| Abstract: | Abstract Nitroxides bearing α-phosphorus substituents are obtained by adding various organophosphorus compounds to solutions of 2-methyl, 2-nitroso propane (M.N.P.); furthermore, the action of nitric oxide on tetraethylpyrophosphite provides the first example of an αα' diphosphorylnitroxide. The nitroxides are identified by E.S.R. and mechanisms are proposed to explain their formation. The present work clearly shows that M.N.P. is not a good scavenger with which to study the radical reactions involving organophosphorus. |
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