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PREPARATION OF PHOSPHORANES FROM TRIVALENT PHOSPHORUS COMPOUNDS AND 1,2-DIOXANE
Authors:Norman J. De'ath  Donald B. Denney
Affiliation:School of Chemistry, Rutgers University, The State University of New Jersey , New Brunswick, N. J., 08903
Abstract:Abstract

1,2-Dioxane has been allowed to react with a variety of trivalent phosphorus compounds. In some cases pentacoordinate phosphorus compounds were formed, whereas in others tetrahydrofuran and the appropriate phosphoryl containing compound were produced. The mechanism of the reaction is discussed.
Keywords:triphogene  α-Ureidoalkylphosphonate  α-aminoalkylphosphonate  o-aminobenzoic acid  α-aminocarboxylate
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