S-1805/Ag/Au Hybrid Transparent Electrodes for ITO-free Flexible Organic Photovoltaics |
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Authors: | WEN Xuemei YI Fangshun JI Jinhai BI Yangang ZHANG Wenyi WANG Wenquan |
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Institution: | 1. State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, P. R. China;
2. College of Physics, Jilin University, Changchun 130012, P. R. China;
3. Systems Engineering Research Institute, Beijing 100094, P. R. China |
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Abstract: | We fabricated an S-1805/Ag/Au hybrid transparent electrode based on 4.4 nm ultrathin Au film, which exhibited a high transparency(T=78% at 550 nm), a low sheet resistance(Rs=70 Ω/sq), and an extremely smooth surface(roughness=0.37 nm). The three-dimensional(3D) island growth mode of 4.4 nm Au film was resisted by the chemical bonding effect of the nonconductive S-1805 film and the wetting behavior of 0.6 nm Ag layer. The S-1805/Ag/Au hybrid transparent electrodes were used as the replacement of ITO anodes in flexible organic photovoltaics(OPVs), and the S-1805/Ag/Au-based OPVs resulted in the similar power conversion efficiency compared to ITO-based devices. High flexibility and mechanical robustness were demonstrated in the ITO-free OPVs without obvious degeneration in device performance after over 2000 repeated bending cycles. |
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Keywords: | Ultrathin metal film Hybrid transparent electrode Flexible organic photovoltaics |
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