Reduction of 4-Nitrophenol Using Ficin Capped Gold Nanoclusters as Catalyst |
| |
Authors: | WU Han CAI Huiwu QIAO Juan QI Li |
| |
Affiliation: | 1. School of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, P. R. China;2. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Analytical Chemistry for Living Biosystems, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;3. School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China |
| |
Abstract: | Conversion of nitroarenes to aminoarenes has attracted great attention in pharmaceutical industry, agricultural production, environmental protection and chemical catalysis area. In this work, ficin capped gold nanoclusters(ficin@AuNCs) were prepared for the reduction of 4-nitrophenol to 4-aminophenol. The proposed catalyst was characterized by transmission electron microscopy, dynamic light scattering, fluorescence spectra and UV-Vis spectra. With NaBH4 as the reducing agent, the reduction reaction could carry out completely within 10 min at 25℃. Interestingly, the resultant catalyst exhibited size-related properties in the reduction, smaller ficin@AuNCs exhibited higher catalytic activity. Its present pseudo-first-order rate constant was found to be 2.95×10‒3 s‒1 and the catalytic activation energy was 27.7 kJ/mol. Moreover, ficin@AuNCs-based catalyst displayed good stability, heading to 4-nitrophenol conversion of 98.5%-100.0% after six consecutive cycles. It has shown a great potential in construction of unique catalysts based on AuNCs for reduction reaction. |
| |
Keywords: | Ficin capped gold nanocluster 4-Nitrophenol 4-Aminophenol Catalytic activation |
本文献已被 维普 万方数据 等数据库收录! |
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
|
点击此处可从《高等学校化学研究》下载全文 |
|