(2,2′‐Bipyridine‐κ2N,N′)(2,3‐naphthalenediolato‐κ2O,O′)palladium(II) and (2,2′‐biquinoline‐κ2N,N′)(2,3‐naphthalenediolato‐κ2O,O′)palladium(II) |
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Authors: | Nobuo Okabe Kana Hagihara Mamiko Odoko Yasunori Muranishi |
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Abstract: | In the title compounds, [Pd(C10H6O2)(C10H8N2)], (I), and [Pd(C10H6O2)(C18H12N2)], (II), each PdII atom has a similar distorted cis‐planar four‐coordination geometry involving two O atoms of the 2,3‐naphthalenediolate dianion and two N atoms of the 2,2′‐bipyridine or 2,2′‐biquinoline ligand. The overall structure of (I) is essentially planar, but that of (II) is not, as a result of intramolecular overcrowding leading to bowing of the biquinoline ligand. |
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