A two‐dimensional network of R(16) and R(8) rings in trans‐bis(4‐amino­pyridine‐κN1)­bis­(benzoato‐κ2O,O′)­copper(II) benzene 0.75‐solvate

The structure of the title supramolecular complex, Cu(C₇H₅O₂)₂(C₅H₆N₂)₂]·0.75C₆H₆, has been determined. The Cu²⁺ ion lies on an inversion centre and is coordinated by four O atoms of two opposing benzoate mol­ecules and two pyridine N atoms of two opposing amino­pyridine mol­ecules. The partially occupied benzene site lies across a twofold rotation axis. The crystal structure is dominated by two‐dimensional networks containing two different hydrogen‐bonded rings (16) and (8)].