catena‐Poly[[di‐μ‐benzoato‐κ4O:O′‐disilver(I)]‐μ‐N,N′‐bis(2‐fluorobenzylidene)butane‐1,4‐diamine‐κ2N:N′] |
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Authors: | Zhong‐Lu You Hai‐Liang Zhu |
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Abstract: | The title complex, [Ag2(C7H5O2)2(C18H18F2N2)]n, is a dinuclear silver(I) compound with one inversion centre between pairs of Ag atoms and another at the mid‐point of the central C—C bond in the butane‐1,4‐diamine moiety. Each of the smallest repeat units consists of two silver(I) cations, two benzoate anions and one N,N′‐bis(2‐fluorobenzylidene)butane‐1,4‐diamine Schiff base ligand. Each AgI ion is three‐coordinated in a trigonal configuration by two O atoms from two benzoate anions and one N atom from a Schiff base ligand. The di‐μ‐benzoato‐disilver(I) moieties are linked by the bridging Schiff base ligand, giving zigzag polymeric chains with an [–Ag⋯Ag—N—C—C—C—C—N–]n backbone running along the b axis. |
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