Polysulfonylamines. CLXXI. [Di(methanesulfonyl)amido‐κN]bis(2‐picoline‐κN)copper(I) |
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Authors: | Peter G. Jones,Eva‐Maria Zerbe,Christoph Wö lper |
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Abstract: | The title compound, [Cu(C2H6NO4S2)(C6H7N)2], consists of monomeric molecules in which the Cu atom displays planar but irregular coordination by three N‐atom donors; Cu—N = 2.1054 (12) (amide N), 1.9514 (12) and 1.9589 (12) Å, and N—Cu—N = 141.24 (5), 111.54 (5) and 107.20 (5)°. Intramolecular Cu⋯O contacts are observed. The packing involves (interconnected) layer formation via C—H⋯O interactions in two directions, three hydrogen bonds combining to form layers parallel to (101) and five to form layers parallel to (10). |
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