Abstract: | The title compound (D4PyMA), C22H19NO2, exhibits polymorphism after crystallization by slow evaporation from a binary mixture of chloroform and hexane. Long needle‐like crystals have an orthorhombic structure (space group Fdd2), with one molecule in the asymmetric unit, while small tablet‐like crystals exhibit a monoclinic crystal structure (space group P21/n), in which two independent but chemically identical molecules comprise the asymmetric unit. The bond lengths and angles are normal, while the torsion angles around the –C—O– bond linking the diphenyl(4‐pyridyl)methyl and methacrylate groups show the flexibility of the molecule by way of packing effects. The two polymorphs both contain weak C—H⋯π and C—H⋯O/N contacts but have different conformations. |