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Recent progress in metal–organic framework/graphene-derived materials for energy storage and conversion: design,preparation, and application
Authors:Kaixi Wang  Kwun Nam Hui  Kwan San Hui  Shaojun Peng  Yuxi Xu
Institution:School of Engineering, Westlake University, Hangzhou 310024 Zhejiang Province China.; Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa Macau SAR China ; Zhuhai Institute of Translational Medicine, Zhuhai People''s Hospital, Zhuhai Hospital Affiliated with Jinan University, Zhuhai Guangdong 519000 China.; Engineering, Faculty of Science, University of East Anglia, Norwich NR4 7TJ UK
Abstract:Graphene or chemically modified graphene, because of its high specific surface area and abundant functional groups, provides an ideal template for the controllable growth of metal–organic framework (MOF) particles. The nanocomposite assembled from graphene and MOFs can effectively overcome the limitations of low stability and poor conductivity of MOFs, greatly widening their application in the field of electrochemistry. Furthermore, it can also be utilized as a versatile precursor due to the tunable structure and composition for various derivatives with sophisticated structures, showing their unique advantages and great potential in many applications, especially energy storage and conversion. Therefore, the related studies have been becoming a hot research topic and have achieved great progress. This review summarizes comprehensively the latest methods of synthesizing MOFs/graphene and their derivatives, and their application in energy storage and conversion with a detailed analysis of the structure–property relationship. Additionally, the current challenges and opportunities in this field will be discussed with an outlook also provided.

This review summarizes comprehensively the latest methods of synthesizing MOFs/graphene and their derivatives, and their application in energy storage and conversion with a detailed analysis of the structure–property relationship.
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