Correction: Iridium-catalyzed enantioselective olefinic C(sp2)–H allylic alkylation

The first iridium-catalyzed enantioselective olefinic C(sp²)–H allylic alkylation is developed in cooperation with Lewis base catalysis. This reaction, catalyzed by cinchonidine and an in situ generated cyclometalated Ir(i)/phosphoramidite complex, makes use of the latent enolate character of an α,β-unsaturated carbonyl compound, namely coumalate ester, to introduce an allyl group at its α-position in a branched-selective manner in moderate to good yield with good to excellent enantioselectivities (up to 98?:?2 er).

The first iridium-catalyzed enantioselective allylic alkylation of an olefinic C(sp²)–H bond – that of an α,β-unsaturated carbonyl compound, is developed in cooperation with Lewis base catalysis.