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(+)‐Camphor­acetic acid: catemeric hydrogen bonding in a γ‐keto acid
Authors:Hugh W Thompson  Marie L Cot  Roger A Lalancette
Abstract:The title compound, (1R)‐4,7,7‐tri­methyl‐3‐oxobi­cyclo­2.2.1]­heptane‐2‐endo‐acetic acid, C12H18O3, like its lower homolog, forms carboxyl‐to‐ketone hydrogen‐bonding catemers (Z′ = 2) O⋯O = 2.729 (5) and 2.707 (5) Å, and O—H⋯O = 165 and 170°] with screw‐related components. The two mol­ecules of the asymmetric unit differ slightly in conformation and produce two counter‐aligned hydrogen‐bonding chains, both aligned with the b axis. Close intermolecular C—H⋯O=C contacts exist for the ketone group of one mol­ecule and for both the ketone and carboxyl functions in the other.
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