{4‐Bromo‐2‐[2‐(5‐bromo‐2‐oxidobenzylideneaminomethyl)phenyliminomethyl]phenolato‐κ4O,N,N′,O′}nickel(II) |
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Authors: | Santu Chakraborty B. Samanta C. R. Chowdhury S. Mitra Alok K. Mukherjee |
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Abstract: | In the title complex, [Ni(C21H14Br2N2O2)], the NiII atom is coordinated by the two imine N and two phenolate O atoms of the Schiff base ligand in a tetrahedrally distorted square‐planar geometry. The Ni—N and Ni—O distances are within the ranges expected for Ni–Schiff base derivatives. Intermolecular C—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers, forming (12) (A) and (10) (B) rings. These dimers combine to form a supramolecular ABAB… aggregate which propagates along the [100] direction. |
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