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Azido­[1,1′‐bis­(di­phenyl­phosphino)­ferrocene](penta­methyl­cyclo­penta­dienyl)­rhodium(III) hexa­fluoro­phosphate
Authors:Won Seok Han  Soon W Lee
Abstract:In the title compound, azido‐2κN‐bis­μ‐(1η5:2κP)‐di­phenyl­phosphino­cyclo­penta­dienyl]2(η5)‐penta­methyl­cyclo­penta­di­enyl]­iron(III)­rhodium(III) hexa­fluoro­phosphate, {Rh(C10H15)(N3)}{Fe(μ‐C17H14P)2}]PF6 or FeRh(C10H15)(μ‐C17H14P)2(N3)]PF6, the coordination sphere of RhIII can be described as pseudo‐tetrahedral, composed of two P atoms from a 1,1′‐bis­(di­phenyl­phosphino)­ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C5Me5 (Cp*) ligand. The two cyclo­penta­dienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh?Fe distance is 4.340 (2) Å.
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