Azido[1,1′‐bis(diphenylphosphino)ferrocene](pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate |
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Authors: | Won Seok Han Soon W Lee |
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Abstract: | In the title compound, azido‐2κN‐bisμ‐(1η5:2κP)‐diphenylphosphinocyclopentadienyl]2(η5)‐pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate, {Rh(C10H15)(N3)}{Fe(μ‐C17H14P)2}]PF6 or FeRh(C10H15)(μ‐C17H14P)2(N3)]PF6, the coordination sphere of RhIII can be described as pseudo‐tetrahedral, composed of two P atoms from a 1,1′‐bis(diphenylphosphino)ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C5Me5 (Cp*) ligand. The two cyclopentadienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh?Fe distance is 4.340 (2) Å. |
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